I start: the most important thing is not the desktop, it’s the package manager.
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I wouldn’t use ZFS. Too risky. If a new kernel comes along and ZFS fails to build or something, my system will be unbootable.
Btrfs scratches my copy-on-write/checksum/integrated RAID itch well enough anyway.
Nix and ubuntu have in kernel support. Void’s module build system also prevents this situation. I use nix and void, so have never faced this problem.